MATERIAL SAFETY DATA SHEET
This Material Safety Data Sheet complies with the United States Occupational Safety and Health Administration (OSHA) Hazard Communication Standard, 29 CFR 1910.1200.
1.
Product and
Supplier Identification
Product: Stain Remover that Really Works
Product Use: Wipe on plating solutions for stained glass crafts.
Supplier: Novacan Industries Ltd.
856 Washington Drive,
Port Moody, BC Canada V3L 5B5
Emergency Telephone: (604) 986-4617
Manufacturer: As above
2.
Composition
|
Component |
% (w/w) |
Exposure Limits |
|
Fluoboric Acid (CAS No.16872-11-0) |
35-40 |
OSHA (PEL): 2.5
mg/m3 for fluorides ACGIH (TLV): 2.5 mg/m3 for fluorides |
3.
Hazards
Identification
Routes
of Entry: (under
normal conditions of use)
Skin Contact: Major Eye Contact: Major Ingestion: Major Inhalation: Major
Effects of
Short-Term (Acute) Exposure:
Inhalation: Inhalation of vapor is serverely irritating to the upper
respiratory tract and can cause burning sensation, severe coughing, wheezing,
aggravation of bronchitis, and asthma.
In severe cases, pulmonary edemas may result.
Skin Contact: Corrosive. Skin contact causes severe burns and
irritation.
Eye Contact: Corrosive. Eye contact causes burns and irritation.
Ingestion: Ingestion is
harmful. May cause irritation and/or systemic toxicity may occur. May be fatal.
Effects of
Long-Term (Chronic) Exposure:
Exposure to fluorides over years may produce embrittlement and
decalcificaiton of bones, and increased calcification of ligaments and
vertebrae resulting in spinal stiffness (fluorosis). cause redness, swelling
and pain (dermatitis). No evidence of carcinogenicity in human studies.
Hazards
Identification, continued
Medical
Conditions Aggravated By Exposure:
Exposure could aggravate any skin irritations
or respiratory ailments.
4.
First Aid
Measures
Eye Contact: Immediately flush eye(s) with running water for 15 minutes. Lift the upper and lower lids frequently to rinse thoroughly. Get medical attention immediately.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion: If swallowed, do not induce vomiting. Rinse mouth with water and give large quantities of milk or milk of magnesia. Never give anything by mouth to an unconscious person. Get medical attention immediately.
5.
Fire Fighting
Measures
Flash point: Not Applicable
Autoignition temperature: Not applicable.
Lower Explosive Limit: Not established
Upper
Explosion Limit: Not established
Sensitivity to Impact: Not sensitive.
Sensitivity to Static Discharge: Not sensitive.
Hazardous Combustion Products: Toxic and corrosive fluoride compounds may be released in a fire situation.
Extinguishing Media: No specific recommendation. Use media to suppress surrounding fire, for example, water, carbon dioxide, or foam.
Fire
Fighting Instructions: Fire fighters should wear full protective clothing and
NIOSH-approved self-contained breathing apparatus with full facepiece operated
in the pressure demand or other positive pressure mode.
NATIONAL
FIRE PROTECTION ASSOCIATION (NFPA) HAZARD INDEX:
HEALTH: 2 - Short exposure could cause serious temporary or residual
injury.
FLAMMABILITY: 0 - Will not burn.
REACTIVITY: 0 - Not reactive when mixed with water.
SPECIFIC HAZARDS: Corrosive
6.
Accidental
Release Measures
Personal Protection: Evacuate
unnecessary personnel from spill area. Wear appropriate personal protective
equipment as specified in section 8 while cleaning the spill. Do not touch
spilled product without proper personal protection. Ventilate area of leak or
spill.
Environmental Precautions: Implement spill
control plan. Stop or reduce
leak if safe to do so. Prevent from entering sanitary or storm sewers, or
waterways.
Remedial Measures: Restrict access to area until completion of cleanup. Use all appropriate
personal protective equipment. Contain and recover liquid when possible.
Neutralize with alkaline material (soda ash, lime), then absorb with an inert
material (e. g., vermiculite, dry sand, earth), and dispose of in DOT approved
waste containers. Do not use combustible materials, such as saw dust. Notify government occupational
health and safety and environmental authorities as per applicable regulations. Comply with all
applicable governmental regulations on spill reporting and handling and
disposal of waste. It is recommended that each user establish a spill
prevention, control and counter measure plan. Such a plan should include
procedures applicable to proper storage, control and clean-up of spills,
including reuse or disposal as appropriate.
7.
Handling and
Storage
Handling
Procedures: Ensure adequate
ventilation. Have emergency equipment readily available. Keep containers closed
when not in use. Keep soda ahs nearby for neutralization. Do not eat, drink or
smoke in ares where the product is being used. Wash face and hands thoroughly after handling and before eating,
drinking, or using tobacco products. Beware of getting in cuts.
Storage: Store
in a cool, dry, well-ventilated area. Keep containers closed. Keep storage area
separate from populated work areas.
8.
Exposure
Controls, Personal Protection
Engineering Controls: Use local
mechanical exhaust ventilation capable of maintaining emissions at the point of
use below the PEL.
Respiratory
Protection: Use NIOSH approved respirator for protection as necessary.If the exposure limit is exceeded, a full
facepiece respirator with an acid gas cartridge and dust/mist filter may be
worn up to 50 times the exposure limit.
WARNING: Air purifying respirators do not
protect workers in oxygen-deficient atmospheres.
Skin protection: Wear protective
acid resistant clothing and gloves.
Eye and Face Protection: Eye protection is
required. Chemical safety
goggles are recommended. It is generally recognized that contact lenses whould
not be worn when working with chemicals because contact lenses can contribute
to the severity of an eye injury.
Footwear: As required by worksite rules.
Other: Have a safety
shower and eye wash station readily available in the immediate work area.
9.
Physical and
Chemical Properties
Appearance: Clear light yellow liquid
Odor: Mild acrid odor
Odor Threshold: Not determined
pH: < 1
Vapor Pressure: 5-10mmHg @ 20oC
Solubility: Completely soluble in water
Vapor Density: Not determined
Freezing Point Not determined
Boiling Point: 113 oC
Critical Temperature: Not applicable.
Relative Density: 1.18
(water = 1)
Partition Coefficient: No data
Evaporation Rate: 1 (BuAc =1)
10.
Stability and
Reactivity
Chemical
Stability: Stable. NOTE: Releases toxic compouds with heat.
Incompatibility: Active metals, alkalis.
Hazardous
Decomposition Products: Boron trifluoride and hydrogen fluoride on decomposition.
Product will react with most metals to release flammable hydrogen gas.
Hazardous
Polymerization: Will not occur.
11.
Toxicological
Information
Acute Exposure: Not determined.
Chronic Exposure: See Section 3.
Exposure Limits: See Section 2.
Irritancy: See Section 3.
Sensitization: See Section 3.
Carcinogenicity: See Section 2
Teratogenicity: Not available
Reproductive toxicity: Not available
Mutagenicity: Inconclusive results
Synergistic products: None reported.
12.
Ecological
Information
Environmental toxicity: No data available.
Biodegradability: No data available.
13.
Disposal
Considerations
Neutralize residues and consult the appropriate Federal, State and
Local regulatory agencies to ascertain proper disposal procedures. Depending on
usage, after use byproducts may contain solder and/or other metals. It is
recommended that each user take into account the additional contaminants
introduced during usage when disposing and handling of waste.
14.
Transport
Information
Department of Transport (49 CFR): Fluoboric Acid, Solution, Class 8, UN 1775, P.G. II
International Air Transport Association (IATA): Fluoboric Acid, Solution, Class 8, UN 1775, P.G. II
International Maritime Organization (IMO): Fluoboric Acid, Solution, Class 8, UN 1775, P.G. II
15.
Regulatory
Information
UNITED STATES – FEDERAL REGULATIONS:
TOXIC SUBSTANCES CONTROL ACT (TSCA):
All
components are listed in the inventory.
OSHA, 29 CFR 1910, Subpart Z: Meets the
criteria for a hazardous substance.
CERCLA, 40 CFR 302: Not listed
SARA 302, 40 CFR 355: Not listed
SARA 313, 40 CFR 372: Not listed
SARA 311/312, 40 CFR 370: Immediate (Acute)
Health, Delayed (Chronic) Health.
16. Other Information
Preparation Date: September 25, 2001
Prepared by: Kel-Ex
Agencies Ltd.,
Comments: This Material Safety Data Sheet was prepared using information provided by
Novacan Industries Ltd., and CCINFO. The information in the
Material Safety Data Sheet is offered for your consideration and guidance when
exposed to this product. Novacan Industries Ltd., expressly disclaims all
expressed or implied warranties and assumes no responsibilities for the
accuracy or completeness of the data contained herein. The data in this MSDS
does not apply to use with any other product or in any other process.
Revisions: Revision January 20, 2004 (1)